By R. Přibil, R. Belcher, H. Freiser
Analytical functions of EDTA and similar Compounds examines the analytical functions of ethylenediaminetetra-acetic acid (EDTA) and similar compounds. This booklet additionally considers the “passive” function of those components, that's, their screening (masking) houses, which drastically increase the selectivity of the reactions in universal use.
This textual content comprises six chapters prepared into sections. the 1st half offers with the makes use of of EDTA and its derivatives in a few fields of chemical research. After delivering an outline of the historical past at the back of the advance of EDTA as an analytical reagent, this publication discusses to the character of equilibria of complexes and the equipment utilized in their research. the subsequent bankruptcy is devoted to the reactions of “classical” gravimetric research, together with the precipitation reactions through natural reagents. The bankruptcy on colorimetry contains a part on “colored complexing agents,” which might be used additionally in colorimetric determinations of a few components. this article concludes by means of comparing using EDTA as a overlaying agent in colorimetry.
This e-book may be of curiosity to scholars and practitioners operating in analytical chemistry and similar disciplines, together with polarography, chromatography, electrophoresis, flame photometry, and qualitative research.
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Additional info for Analytical Applications of EDTA and Related Compounds
And STED^ÍER, R . , Helv. chim. acta 2 8 , 1 1 3 3 ( 1 9 4 5 ) . 3 8 . , COURTNEY, R . C . and MARTELL, A . , / . Am. Chem. Soc. 7 4 , 5 0 5 7 ( 1 9 5 2 ) . 3 9 . , COURTNEY, R . C . and MARTELL, A. , / . Am. Chem. Soc. 7 5 , 2 1 8 5 ( 1 9 5 3 ) . 4 0 . TOREN, P . E. and KOLTHOFF, I . , / . Am, Chem. Soc. 7 7 , 2 0 6 1 ( 1 9 5 5 ) . 4 1 . Brit. Patent 4 9 6 , 7 8 1 . 4 2 . U . S . Patent 2 , 4 0 7 , 6 4 5 . 4 3 . U . S . Patent 2 , 1 0 3 , 5 0 5 . 4 4 . SCHWARZENBACH, G . and ACKERMANN, H . , Hel^.
13). This is due to the thallium complex having a much smaller diffusion coefficient than the free ion . Over the whole range from an acid to an alkaline p H , the irreversible wave of the Bior Sb-EDTA complex is observed. The waves of the Cd, P b and Sn complexes can only be observed in the acid range of p H . These cannot be reduced above p H = 4. A Polarographie wave will not be found over the whole potential range of the dropping mercury electrode in the case of Zn, C o " , Ni and M n complexes with E D T A .
CH2 O . CH2 . CH2 . HN> :H2 . CH2/ THE NATURE OF EQUILIBRIA OF COMPLEXES AND METHODS OF STUDY 43 XI. Bis-2-aminoethylether-Ar,iV,A^',iV'-tetra-acetic acid . Dissociation constants and stability con stants measured at 20°C and μ = 0-1 in KNO3. (pK^ = 1-9; = 2-67; pKs = 8-82; püC^ = 9-49) TABLE Cation Complex logi^^Y Cation Compiex lOg^MY Mg2+ Ca^^ Ba2+ Mn^^ MgY^CaY^BaY^ΜηΥ2- 8-3 10-0 8-2 13-2 Cu2+ Zn2+ Cd2+ CuY^ΖηΥ2CdY^- 17-8 15-3 17-8 T A B L E XII. l,2-bis-i5-aminoethoxyethane-MA^,^',A^'-tetra-acetic acid .
Analytical Applications of EDTA and Related Compounds by R. Přibil, R. Belcher, H. Freiser